Electrochemical storage of hydrogen in NTs
Ch. Nuetzenadel, A. Zuettel, D. Chartouni, Ch. Emmenegger, and L. Schlapbach
One still unsolved problem for the use of hydrogen
as clean fuel is the safe and efficient storage of hydrogen.
Currently cryo tanks, gas bottles or metal hydrides
are used. Important parameters are weight and volume
density, cost and safety. Recent publications [1-3] claimed
that large amounts of hydrogen can be stored reversibly in
carbon nanotubes from the gas phase. Similar to a gas
phase experiment where the storage material is charged
with hydrogen by increasing
the pressure one can also do this electrochemically.
We report [4] that carbon nanotube can be charged reversibly with
hydrogen with amounts exceeding metal hydrides.
Samples with different degrees
of purity were used and the capacity scales roughly with the percentage of
nanotubes in the sample.
[1] Hill, 'Green Cars go farther with graphite', New Scientist, 12/28 December
1996
[2] Dillon, 'Storage of hydrogen in single-walled carbon nanotubes', Nature Vol
386, 27 March 1997, pp 377
[3] Chambers, J. Phys. Chem. B 102 (1998) 4253
[4] Nuetzenadel, Electrochem. and Sol. State Lett., 2 (1) 30 (1999)
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