TABLE OF CONTENTS
| Part I: Morphology, Characterization, and Formation of Nanotubes | |
| Filling Carbon Nanotubes Using an Arc Discharge | 1 |
| A. Loiseau, N. Demoncy, O. Stéphan, C. Colliex, and H. Pascard | |
| Simulation of STM Images and STS Spectra of Carbon Nanotubes | 17 |
| Ph. Lambin, V. Meunier, and A. Rubio | |
| Applications Research on Vapor-Grown Carbon Fibers | 35 |
| G.G. Tibbetts, J.C. Finegan, J.J. McHugh, J.-M. Ting, D.G. Glasgow, and M.L. Lake | |
| The Growth of Carbon and Boron Nitride Nanotubes: | |
| A Quantum Molecular Dynamics Study | 53 |
| Jean-Christophe Charlier, Xavier Blase, Alessandro De Vita, and Roberto Car | |
| Nanoscopic Hybrid Materials: The Synthesis, Structure | |
| and Properties of Peapods, Cats and Kin | 67 |
| David E. Luzzi and Brian W. Smith | |
| Linear Augmented Cylindrical Wave Method for Nanotubes: | |
| Band Structure of [Cu@C20]oo | 77 |
| Pavel N. D'yachkov and Oleg M. Kepp | |
| Comparative Study of a Coiled Carbon Nanotube by Atomic | |
| Force Microscopy and Scanning Electron Microscopy | 83 |
| P. Simonis, A. Volodin, E. Seynaeve, Ph. Lambin, and C. Van Haesendonck | |
| Investigation of the Deformation of Carbon Nanotube Composites | |
| Through the Use of Raman Spectroscopy | 93 |
| C.A. Cooper and R.J. Young | |
| Electronic States, Conductance and Localization in | |
| Carbon Nanotubes with Defects | 103 |
| T. Kostyrko, M. Bartkowiak, and G.D. Mahan | |
| Physics of the Metal-Carbon Nanotube Interfaces: Charge Transfers, Fermi-Level | |
| "Pinning" and Application to the Scanning Tunneling Spectroscopy | 121 |
| Yongqiang Xue and Supriyo Datta | |
| Single Particle Transport Through Carbon Nanotube Wires: Effect of | |
| Defects and Polyhedral Cap | 137 |
| M.P. Anantram and T.R. Govindan | |
| Carbon Nanotubes from Oxide Solid Solution: A Way to Composite | |
| Powders, Composite Materials and Isolated Nanotubes | 151 |
| Christophe Laurent, Alain Peigney, Emmanuel Flahaut, Revathi Bacsa, and Abel Rousset | |
| Impulse Heating an Intercalated Compound Using a 27.12 MHz Atmospheric | |
| Inductively Coupled Argon Plasma to Produce Nanotubular Structures | 169 |
| Thomas J. Manning, Andrea Noel, Mike Mitchell, Angela Miller, William Grow, | |
| Greg Gaddy, Kim Riddle, Ken Taylor, Joseph Stach, and Thomas Vickers | |
| The Synthesis of Single-Walled Carbon Nanotubes by CVD Catalyzed | |
| with Mesoporous MCM-41 Powder | 181 |
| Jun Li, Mawlin Foo, Ying Wang, Hou Tee Ng, Stephan Jaenicke, Guoqin Xu, and Sam F.Y. Li | |
| Part II: Mechanical and Chemical Properties of Nanotubes | |
| Mechanical Properties and Electronic Transport in Carbon Nanotubes | 195 |
| J. Bernholc, M. Buongiorno Nardelli, J.-L. Fattebert, D. Orlikowski, C. Roland, and Q. Zhao | |
| Electrochemical Storage of Hydrogen in Carbon Single Wall Nanotubes | 205 |
| Christoph Nützenadel, Andreas Züttel, Christophe Emmenegger, | |
| Patrick Sudan, and Louis Schlapbach | |
| Direct Measurement of Binding Energy Via Adsorption of Methane on SWNT | 215 |
| S. Weber, S. Talapatra, C. Journet, and A. Migone | |
| Part III: Electronic Properties of Nanotubes | |
| Electrical Properties of Carbon Nanotubes: | |
| Spectroscopy, Localization and Electrical Breakdown | 223 |
| Phaedon Avouris, Richard Martel, Hiroya Ikeda, Mark Hersam, | |
| Herbert R. Shea, and Alain Rochefort | |
| Field Emission of Carbon Nanotubes from Various Tip Structures | 239 |
| Jisoon Ihm and Seungwu Han | |
| First and Second-Order Resonant Raman Spectra of | |
| Single-Walled Carbon Nanotubes | 253 |
| M.S. Dresselhaus, M.A. Pimenta, K. Kneipp, | |
| S.D.M. Brown, P. Corio, A. Marucci, and G. Dresselhaus | |
| On the pi-pi Overlap Energy in Carbon Nanotubes | 275 |
| G. Dresselhaus, M.A. Pimenta, R. Saito, J.C. Charlier, S.D.M. Brown, | |
| P. Corio, A. Marucci, and M.S. Dresselhaus | |
| Electronic and Mechanical Properties of Carbon Nanotubes | 297 |
| L. Forró, J.-P. Salvetat, J.-M. Bonard, R. Bacsa, N.H. Thomson, S. Garaj, | |
| L. Thien-Nga, R. Gaál, A. Kulik, B. Ruzicka, L. Degiorgi, A. Bachtold, | |
| C. Schönenberger, S. Pekker, K. Hernadi | |
| Low Energy Theory for STM Imaging of Carbon Nanotubes | 321 |
| C.L. Kane and E.J. Mele | |
| Quantum Transport in Inhomogeneous Multi-Wall Nanotubes | 333 |
| S. Sanvito, Y.-K. Kwon, D. Tománek, and C.J. Lambert | |
| Conductivity Measurements of Catalytically Synthesized Carbon Nanotubes | 349 |
| M. Ahlskog, R.J.M. Vullers, E. Seynaeve, C. Van Haesendonck, A. Fonseca, and J.B. Nagy | |
| Part IV: Applications of Nanotubes | |
| Fabrication of Full-Color Carbon-Nanotubes Field-Emission Displays: | |
| Large Area, High Brightness, and High Stability | 355 |
| W.B. Choi, Y.H. Lee, D.S. Chung, N.S. Lee and J.M. Kim | |
| Free Space Construction with Carbon Nanotubes | 365 |
| George D. Skidmore, Matthew Ellis, and Jim Von Ehr | |
| List of Participants | 379 |
| Glossary of Common Abbreviations | 393 |
| Index | 395 |
SUBJECT INDEX
| Adsorption |
| heat of, 217 |
| hydrogen, see Hydrogen storage |
| isotherms, 217 |
| methane, 215 |
| Arc-discharge synthesis, 1, 67-68, 94, 297 |
| Atomic force microscopy (AFM), 83, 85, 300 |
| tapping mode, 85 |
| Attachment of nanotubes, 371 |
| Bucky-paper, 370 |
| Bundles of nanotubes, see Ropes of nanotubes |
| C60 molecules, 2 |
| in peapods, see Peapods |
| Carbon arc, see Arc-discharge synthesis |
| Carbon fibers, 11 |
| adhesion of, 39 |
| air-etched, 47 |
| composites of, see Composites of fibers |
| continuous formation of, 35-36 |
| elastic modulus, 41, 43-44, 46, 48-49 |
| electric conductance, 49 |
| graphitized, 47 |
| infiltration of polymers, 38 |
| modulus, see elastic modulus |
| properties improvement, 48 |
| shear strength, 47 |
| tensile strength, 41-43, 46 |
| vapor-grown, 35-36 |
| Carbon filaments, 35 |
| formation of, 35 |
| Carbon nanotubes |
| coiled, see Coiled nanotubes |
| composites, see Composites of nanotubes |
| conductance, see Electric transport |
| defects in, see Defects in nanotubes |
| electric properties, see Electric properties |
| filling, see Filling of nanotubes |
| field emission, see Field electron emission |
| growth, see Growth mechanism |
| magnetic properties, see Magnetic properties |
| mechanical properties, see Mechanical |
| properties |
| morphology, see Morphology of nanotubes |
| purification, see Synthesis of nanotubes, |
| purification |
| ropes of, see Ropes of nanotubes |
| spiral, see Coiled nanotubes |
| synthesis of, see Synthesis of nanotubes |
| transport in, see Electric transport or Thermal transport |
| Catalytic synthesis, 12, 84-85, 152 |
| Chemical composition, 5 |
| Chemical vapor deposition synthesis, 152, 181, 299, 350 |
| Coiled nanotubes, 83-84, 90, 224, 299, 304 |
| pitch of, 90 |
| Combustion, 35 |
| Composites of fibers, 41, 94, 98 |
| electric conductance, 49 |
| Composites of nanotubes, 58, 93, 98 |
| Al2O3-based, 154 |
| deformation of, 93 |
| densification fracture, 164 |
| electric conductance, 166 |
| fracture strength, 165 |
| matrix reinforcement, 100 |
| matrix-nanotube interaction, 102 |
| mechanical properties, 93, 98, 100, 165 |
| MgAl2O4-based, 159 |
| MgO-based, 161 |
| nanotube-matrix interaction, 166 |
| metal-oxide composites, 152-153 |
| Conductance of nanotubes, see Electric transport |
| Construction using nanotubes, 365 |
| attachment, see Attachment of nanotubes |
| manipulation, see Manipulation of nanotubes |
| multiple tube assembly, 374 |
| weaving, 374 |
| Contact potential, 19 |
| Cutting of nanotubes, 373 |
| Defects in nanotubes, 28, 103, 128 |
| dilute disorder, 113 |
| formation of, 31 |
| heptagon, 84 |
| interference effects, 112 |
| local charge neutrality, 131 |
| localization length, 116 |
| Lyapunov exponents, 116 |
| pentagon, 84 |
| pentagon-heptagon pair, 29, 90 |
| scattering from defects, 109 |
| Stone-Wales, 17, 30-31, 196 |
| Deformation of nanotubes, 95 |
| addimer-induced transformation, 198 |
| Diffraction, 2, 7 |
| Doping of nanotubes, 231 |
| Electric properties, 223 |
| metallic CNTs, 22 |
| semiconducting CNTs, 22, 231 |
| work function of CNTs, 362 |
| Electric transport 195, 223, 231 |
| Aharonov-Bohm effect, 306, 308 |
| anti-resonance, 144 |
| ballistic, 118, 137, 199, 305, 309, 334, 350, 352 |
| bent nanotubes, 236 |
| bond rotation defect, 144 |
| breakdown, 223, 229 |
| capped nanotubes, 137, 143 |
| coherence length, 223, 226, 309 |
| conductance, 22, 103-104, 129 |
| conductance quantization, 305, 333 |
| contact resistance, 349 |
| current densities, 229 |
| current-voltage characteristics, 351 |
| defect scattering, 137, 200 |
| dependence on energy, 339, 343 |
| diffusive, 308 |
| effect of tube diameter, 141 |
| fabrication of contacts, 351 |
| inhomogeneous multi-wall nanotubes, 342 |
| Kondo scattering, 228 |
| Landauer-Büttiker formalism, 107, 336 |
| localization, 118, 223 |
| localization length, 140 |
| Luttinger liquid behavior, 228, 305-306, 310 |
| magnetoresistance, 227, 308 |
| multi-wall nanotubes, 307, 338, 349 |
| non-ohmic, 231 |
| ohmic, 118 |
| quantum interference, 306 |
| quasi-ballistic, 309 |
| quasiparticle lifetime, 113 |
| resonances in transmission, 138 |
| scattering from, 322 |
| scattering theory of, see Scattering theory |
| single-wall nanotubes, 307 |
| spin-orbit scattering, 228 |
| strong isolated defects, 141 |
| strong localization, 227 |
| sub-band contribution, 141 |
| superconductivity, 352 |
| temperature-dependent resistance, 307 |
| transmission gap, 142 |
| transmission probability, 138-140, 143, 336 |
| twisted nanotubes, 236 |
| universal conductance fluctuations, 227 |
| weak localization, 225 |
| weak uniform disorder, 140 |
| zero-bias anomaly, 228, 310 |
| Electrodes |
| graphite, 2, 6 |
| Electrolysis, 2 |
| Electron diffraction, 2 |
| Electron energy loss spectroscopy (EELS), 2, 7 |
| Electron irradiation, 302 |
| Electron spin resonance, 311 |
| multi-wall tubes, 312 |
| single-wall tubes, 313 |
| Electronic structure, 18, 123, 126 |
| band dispersion, 77, 79-80, 276 |
| band-bending in semiconducting nanotubes, 232 |
| charge density waves, 322 |
| charge transfer at interfaces, see Interface with metals, charge transfer |
| D-band, 292 |
| density matrix, 322-323 |
| density of states, 139, 240, 253, 255-256, 311 |
| electron spin g-factor, 312 |
| electronic states, 103 |
| Fermi-level pinning, 121 |
| G' band, 293 |
| graphite, 20, 264, 281-282 |
| localized states, 103, 240 |
| metallic nanotubes, 278, 281 |
| multi-wall nanotubes, 338 |
| particle-hole state symmetry, 276 |
| pp-pi matrix element gamma0, 256, 275, 311 |
| pseudogaps, 24 |
| self-consistent potential, 124 |
| semiconducting nanotubes, 278, 281 |
| single-wall nanotubes, 17, 103, 137, 223, 321 |
| Slonczewski-Weiss-McClure band model, 275 |
| spin relaxation, 312 |
| spin susceptibility, 311 |
| spin-orbit coupling, 312 |
| tunneling states, 322 |
| van Hove singularities, 24, 280, 283, 309 |
| Energy storage |
| electrochemical double layer, 209 |
| Field electron emission |
| closed nanotubes, 315 |
| cold cathode, 355, 362 |
| current stability, 363 |
| current-voltage characteristics, 360 |
| densities of emitters in displays, 363 |
| display brightness, 359 |
| display characteristics, 359 |
| emission current, 362 |
| emitter array, 248 |
| Fowler-Nordheim theory, 239, 318 |
| field enhancement, 241, 245-248, 316, 360 |
| flat-panel display, 355, 359 |
| isolated multi-wall nanotubes, 314 |
| localized states, 246 |
| luminescence induced by, 317 |
| mechanism, 318 |
| nanotube cathode, 355, 362 |
| nanotube emitter array, 316 |
| onset electric field, 360 |
| open-ended nanotube emitter, 315 |
| uniformity, 360 |
| Filling of nanotubes, 1, 3 |
| by C60, see Peapods |
| by metals, 77, 81 |
| capillarity, 1 |
| Formation process, see Growth mechanism or Synthesis of nanotubes |
| Graphite |
| electrodes, see Electrodes, graphite |
| electronic structure, see Electronic structure, graphite |
| exfoliation of graphite, see Growth mechanism, graphite exfoliation |
| fluorination, see Synthesis of nanotubes, |
| fluorinated graphite |
| phonon structure, see Phonon structure, graphite |
| Graphitization, 12 |
| Growth mechanism, 2, 10, 53 |
| base growth, 163, 191 |
| boron nitride (BN) nanotubes, 53-54, 58, 62-63 |
| carbon nanotubes, 53-54, 190 |
| dynamics, 60 |
| frustration effects, 58 |
| frustration energies, 60 |
| graphite exfoliation, 171 |
| lip-lip interaction, 56 |
| multi-wall nanotubes (MWNTs), 57 |
| single-wall nanotubes (SWNTs), 54 |
| termination, 12 |
| tip-growth, 163, 191 |
| yarmulke-growth, 163 |
| Heat conductance, see Thermal transport |
| Helicity, see Coiled nanotubes, pitch of |
| Hybrid assemblies of nanotubes, 67 |
| Hydrogen storage, 215 |
| capacity, 209 |
| cyclic stability, 207 |
| electrochemical, 205 |
| reaction rate, 209 |
| Hydrogenation of nanotubes, 302 |
| Interface with metals, 121, 124, 127 |
| charge transfer, 124 |
| Inter-wall coupling, 27 |
| Junctions of nanotubes, 30 |
| Light emission, 317 |
| Magnetic properties, 312 |
| Manipulation of nanotubes, 365 |
| attachment, see Attachment of nanotubes |
| Mechanical properties, 195, 297 |
| bending modulus, see Young's modulus |
| disorder, 302 |
| ductile-brittle domain map, 198 |
| elastic modulus, see Young's modulus |
| fracture toughness, 154 |
| mechanical strength, 300 |
| multi-wall nanotubes, 93-94, 100 |
| nanotube composites, see Composites of nanotubes |
| nanotube ropes, 300 |
| tensile strength, 94 |
| Young's modulus, 94, 300 |
| Metal-induced gap states (MIGS), 122, 132 |
| Moiré super-pattern, 27 |
| Molecular dynamics simulations, 53 |
| Morphology of nanotubes, 58, 83 |
| achiral, see non-chiral |
| armchair, 22, 24, 54, 60 |
| bundled, see Ropes of nanotubes |
| capped, 216 |
| chiral, 17, 25-26 |
| coiled, see Coiled nanotubes |
| diameter, 162, 187 |
| Euler's theorem, 55 |
| helical, see Coiled nanotubes |
| multi-wall, 10, 27, 56 |
| non-chiral, 25 |
| rings, see Coiled nanotubes |
| rippling in bent nanotubes, 304 |
| ropes, see Ropes of nanotubes |
| single-wall, 10, 17, 54, 93-95, 122 |
| spiral, see Coiled nanotubes |
| symmetry, 27-28 |
| terminating caps, 23, 27, 54 |
| twisted, 28, 236 |
| zig-zag, 24, 54, 61 |
| Nanoencapsulates, 177 |
| Nanotube ropes, see Ropes of nanotubes |
| Nanotubes |
| boron nitride, 53 |
| carbon, see Carbon nanotubes |
| Nanowires, 2, 9-10 |
| Optical conductivity of nanotubes, 306 |
| Peapods, 67-68 |
| Phase diagrams, 13-14 |
| Phonon structure |
| anti-Stokes spectra, 258 |
| combination modes, 266, 270 |
| D-band, 261 |
| dependence on tube diameter, 256 |
| G'-band, 261 |
| graphite, 264 |
| overtone modes, 266 |
| radial breathing mode, 253, 256 |
| resonant Raman scattering, see Raman |
| spectroscopy, resonant |
| Stokes spectra, 258 |
| tangential stretching mode, 253, 256 |
| Pulsed laser vaporization synthesis, 67-68, 94 |
| Quantum dots, 198 |
| Raman spectroscopy, 93, 94 |
| resonant, 253, 256, 287 |
| Ropes of nanotubes, 27,160-161, 182, 189, 374 |
| Scanning electron microscopy (SEM), 83, 85 |
| Scanning tunneling microscopy (STM), 17, 122, 286, 321 |
| atomic corrugation, 24 |
| bias-dependence of STM images in metallic nanotubes, 326 |
| bias-dependence of STM images in semiconducting nanotubes, 327 |
| current-voltage characteristics, 20-21 |
| geometric distortion, 26 |
| images, 20, 24 |
| Scanning tunneling spectroscopy (STS), 17, 22, 121, 129, 286 |
| Scattering theory, 104, 333, 335 |
| transfer matrix approach, 105 |
| Schottky barrier, 122, 132 |
| Spectroscopy, 223, 236 |
| electron, see Electron energy loss |
| spectroscopy (EELS), 2, 7 |
| optical transmission spectroscopy, 286 |
| Raman, see Raman spectroscopy |
| tunneling, see Scanning tunneling spectroscopy (STS) |
| Stability |
| structural, 58 |
| thermal, 229 |
| Strain energy |
| axial, 196 |
| bending, 59 |
| Sulfide, 7-8 |
| Sulfur, 2, 6, 9, 10-12 |
| Surface treatment, 44 |
| Synthesis of nanotubes |
| arc discharge, see Arc-discharge synthesis |
| catalytic, see Catalytic synthesis |
| chemical vapor deposition (CVD), see Chemical vapor deposition synthesis |
| CO disproportionation, 152 |
| electrolysis of molten salts, 151 |
| fluorinated graphite, 172 |
| inductively coupled plasma, 169, 170 |
| mesoporous templates, 182 |
| methane decomposition, 158 |
| powder synthesis, 152 |
| pulsed laser vaporization, see Pulsed laser vaporization synthesis |
| purification of nanotubes, 297 |
| pyrolysis 2, 35, 151 |
| reduction of solid solutions, 152 |
| solar technique, 151 |
| spiral nanotubes, 299 |
| temperature range, 10 |
| Tight-binding formalism, 18 |
| Thermal transport, 229 |
| Topology, see Morphology of nanotubes |
| Transmission electron microscopy (TEM), 2, 36, 68, 84 |
| Tunneling processes, 18 |
| Van Hove singularities, see Electronic structure, van Hove singularities |
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