Discussion Topic Posted for the
NANOTUBE-99 Workshop:
Why are nanotubes not superconducting?
Contact person:
tomanek@msu.edu
This appears to be a true mystery in view of the following facts:
- Nanotubes, same as fullerenes, are characterized by the same type of
sp2 bonding as graphite.
- Graphite, when intercalated, becomes superconducting (albeit at very low
tempeartures). Solid C60, when intercalated, is superconducting
well above 30 K. Electron-phonon coupling is responsible for superconductivity
in these two systems.
- The vibrational spectrum of nanotubes in ropes contains the same
high-frequency modes that cause superconductivity in solid C60.
- Same as in graphite, intercalants have been observed to shift the Fermi
level towards the Van-Hove singularities, causing a significant increase in the
density of states and in the observed conductivity. In solid C60
this increase/onset of conductivity has been accompanied by superconducting
behavior.
1.1 "Effects due to the intercalation process"
by Peter Butzloff, University of North Texas,
Department of Materials Science
1.2 "Experimental Evidence for Superconductivity
through Single-Walled Carbon Nanotubes"
by David Tomanek, Michigan State University
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Last modification:
2020.07.25 (Saturday) 10:13:55 EDT